Modelling of the Temporal Analysis of Products (TAP) Reactor with COMSOL

S. Pietrzyk[1], A. Khodakov[1], and M. Olea[2]
[1]Unite de Catalyse et de Chimie du Solide, USTL-ENSCL-EC Lille, Villeneuve d’Ascq, France
[2]School of Science and Technology, University of Teesside, Middlesbrough, UK
Publié en 2008

A TAP reactor is a fixed-bed catalytic reactor operated in pulse (transient) mode under very low pressures. It has become a very important tool in catalytic studies as it fills the material and pressure gaps existing between practical conditions and high vacuum – monocrystal techniques.

A pretreated solid catalyst maintained at a desired temperature in an evacuated chamber is exposed to a series of very narrow gas pulses.

COMSOL provides an easy way to model the results, particularly when dealing with non-standard experiments. COMSOL models can be converted to scripts and used as central parts of optimization programs for the determination of relevant kinetic constants.

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