LMO Decomposition
Application ID: 129721
Some positive electrode materials are known to deteriorate in overcharged lithium-ion battery cells. Predominantly, manganese containing electrode materials such as LMO and NMC can loose capacity due to manganese dissolving from the materials at overcharge. This decomposition is a chemical reaction driven by protons that originate from solvent oxidation and water. The reaction decreases the electrode volume fraction.
This example models the capacity fade of an LMO vs lithium-foil cell. Results show a drop in both capacity and electrolyte salt concentration for abusive cycling conditions.
This model example illustrates applications of this type that would nominally be built using the following products:
however, additional products may be required to completely define and model it. Furthermore, this example may also be defined and modeled using components from the following product combinations:
The combination of COMSOL® products required to model your application depends on several factors and may include boundary conditions, material properties, physics interfaces, and part libraries. Particular functionality may be common to several products. To determine the right combination of products for your modeling needs, review the Grille des Spécifications and make use of a free evaluation license. The COMSOL Sales and Support teams are available for answering any questions you may have regarding this.